Cross coupling of vinyl triflates and alkyl Grignard reagents catalyzed by niekel(0)-complexes

DOI: 10.1016/S0040-4039(99)00439-6

Source and publish data:

Tetrahedron Letters p. 3101 - 3104 (1999)

Update date:2022-07-30

Topics:

Authors:

Busacca, Carl A.

Eriksson, Magnus C.

Fiaschi, Rita

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Article abstract of DOI:10.1016/S0040-4039(99)00439-6

The scope and limitations of the Nickel(0)-catalyzed cross coupling of vinyl triflates with alkyl Grignard reagents have been studied. The effect of triflate substitution, solvent, and especially ligands have been examined. Ligands which are successful for sp² and sp Grignard reagents fail for sp³ Grignard reagents.

Full text of DOI:10.1016/S0040-4039(99)00439-6

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