Tetrahedron Letters p. 6295 - 6298 (1998)
Update date:2022-09-26
Topics:
Ito, Hajime
Ishizuka, Tomoko
Tateiwa, Jun-Ichi
Hosomi, Akira
A new selective synthetic method of enol esters (O-acylated products) from silyl enol ether and acid chloride in the presence of CuCl is described. This reaction proceeds smoothly in DMI (1,3-dimethyl-2-imidazolidinone) but not in a less polar solvent. The silicon-copper exchange reaction pathway is proposed for this transformation as in the cases of D and alkynylsilane which were previously reported.
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