Journal of Organometallic Chemistry p. 313 - 322 (1987)
Update date:2022-08-03
Topics:
Pankratov, L. V.
Penyagina, I. M.
Zakharov, L. N.
Bochkarev, M. N.
Razuvaev, G. A.
et al.
The selective insertion of sulfur into the Ge-Hg bond in the ionic complex <<(C6F5)3Ge>3Hg>-Cp2CO+ results in the formation of mono-, di- and trithiolate derivatives.The compounds have been characterized by elementary analysis, IR, 19F and 199Hg NMR spectroscopy.The molecular structure of A general scheme for the reaction of vanadocene with cobalticinium germylmercurate has been proposed.The zerovalent triphenylphosphine complex of platinum Pt(PPh3)4 destroys the ionic structure of <<(C6F5)3Ge>2HgI>-(C6H6)2Cr+ to give dibenzenechromium iodide and a polinuclear compound with Ge-Hg-Pt-Ge chain.
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