Chemical Communications p. 1465 - 1466 (1996)
Update date:2022-08-04
Topics:
Garcia, Concepcion Fernandez
McKervey, M. Anthony
Ye, Tao
Intramolecular N-H insertion reactions of α-diazocarbonyl substrates are catalysed by rhodium(II) carboxylates with catalyst-dependent competition with C-H insertion and β-elimination; asymmetric N-H insertion leading to a pipecolic acid derivative with ee up to 45% is achieved using chiral catalysts.
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