Asymmetric catalysis of intramolecular N-H insertion reactions of α-diazocarbonyls

DOI: 10.1039/CC9960001465

Source and publish data:

Chemical Communications p. 1465 - 1466 (1996)

Update date:2022-08-04

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Authors:

Garcia, Concepcion Fernandez

McKervey, M. Anthony

Ye, Tao Ye, Tao

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Article abstract of DOI:10.1039/CC9960001465

Intramolecular N-H insertion reactions of α-diazocarbonyl substrates are catalysed by rhodium(II) carboxylates with catalyst-dependent competition with C-H insertion and β-elimination; asymmetric N-H insertion leading to a pipecolic acid derivative with ee up to 45% is achieved using chiral catalysts.

Full text of DOI:10.1039/CC9960001465

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