Inorganic Chemistry p. 711 - 717 (1964)
Update date:2022-08-04
Topics:
Hayter
The reactions of tetramethylbiphosphine and -biarsine with the carbonyls of nickel, iron, chromium, molybdenum, and tungsten and of tetraphenylbiphosphine with nickel carbonyl have been studied and two types of binuclear complexes identified. The group VI metal carbonyls also give a third type of complex, which is apparently polymeric. The infrared and proton n.m.r. spectra of the complexes are discussed, and a few simple reactions are studied.
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