Single Electron Transfer in Aldol Condensation. The Reaction of Lithium Enolates with Diaryl Ketones

DOI: 10.1021/jo00354a011

Source and publish data:

Journal of Organic Chemistry p. 472 - 476 (1986)

Update date:2022-08-02

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Authors:

Ashby, E. C.

Argyropoulos, J. N.

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Article abstract of DOI:10.1021/jo00354a011

It has been determined by EPR spectroscopy that typical enolate anions react with diaryl ketones by an electron-transfer process to produce paramagnetic intermediates.A kinetic analysis shows that the paramagnetic intermediate formed in the reaction of th

Full text of DOI:10.1021/jo00354a011

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