Tetrahedron Letters p. 5043 - 5046 (1999)
Update date:2022-08-04
Topics:
Matsumoto, Takaji
Murayama, Toshiyuki
Mitsuhashi, Shigeru
Miura, Takashi
Asymmetric synthesis of (S)-5 has been accomplished with an excellent enantiomeric excess by hydrogenation of racemic 5 using ruthenium-BINAP- diamine-KOH system, followed by oxidation. Magnesium enolate of (2S)-2- methoxycyclohexanone [(S)-5] reacts with
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