Reaction of Copper(I) Phenoxide with PhNCS: Formation and X-Ray Structure of a Novel Copper(I) Hexameric Complex

DOI: 10.1039/c39890001803

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1803 - 1804 (1989)

Update date:2022-08-04

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Authors:

Narasimhamurthy, Narasappa

Samuelson, Ashoka G.

Manohar, Hattikudur

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Article abstract of DOI:10.1039/c39890001803

In the presence of phosphites, PhNCS inserts into the Cu^I-OPh bond; the complex formed loses the phosphite and oligomerises to form a unique copper(I) hexamer hexakis<μ-copper(I)> (2), as evidenced from an X-ray crystallographic study.

Full text of DOI:10.1039/c39890001803

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