Protonation at Hydrido Ligands in

DOI: 10.1039/c39920000441

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 441 - 443 (1992)

Update date:2022-08-02

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Authors:

Oglieve, Kay E.

Henderson, Richard A.

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Article abstract of DOI:10.1039/c39920000441

Kinetic studies on the reaction between and anhydrous HCl in tetrahydrofuran show that the formation of ⁺ occurs by two pathways, one involving direct protonation at the metal and the other involving initial attack at a hydrido ligand to generate 2-H2)(PMePh2)4>⁺ which subsequently rearranges to give the pentahydride.

Full text of DOI:10.1039/c39920000441

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Product name:{WH₅(P(C₆H₅)2CH₃)4}⁽¹⁺⁾*Cl^(1-)={WH₅(P(CH₃)(C₆H₅)2)4}Cl

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