Protonation at Hydrido Ligands in

DOI: 10.1039/c39920000441

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 441 - 443 (1992)

Update date:2022-08-02

Topics:

Authors:

Oglieve, Kay E.

Henderson, Richard A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920000441

Kinetic studies on the reaction between and anhydrous HCl in tetrahydrofuran show that the formation of ⁺ occurs by two pathways, one involving direct protonation at the metal and the other involving initial attack at a hydrido ligand to generate 2-H2)(PMePh2)4>⁺ which subsequently rearranges to give the pentahydride.

Full text of DOI:10.1039/c39920000441

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{WH₅(P(C₆H₅)2CH₃)4}⁽¹⁺⁾*Cl^(1-)={WH₅(P(CH₃)(C₆H₅)2)4}Cl

Cas No:66518-96-5

R&D Labs maybe for 66518-96-5

HANGZHOU EVC CHEMICAL CO.,LTD.(expird)

Contact:+86-571-88296056

Address:Room#3001,Zhejiang Chemical Market,No.10,Road Shenban,Hangzhou,Zhejiang,China
CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD

website:http://www.czyys.com

Contact:0086-519-88802789

Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China
Kunshan Yalong Trading Co,.Ltd

Contact:86-512-57621185

Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu，China
Nanjing Chemipioneer Pharma&Tech Co.,Ltd

website:http://www.chemipioneer.com.cn

Contact:+86-25-52685700

Address:Room 305，A Block，Biological-Medicine Building，Business Start-up Center，Xin-ke 1st Road, High-tech development zone，Nanjing city，Jiangsu Province, China
Jiaxing Taixin Pharmaceutical Chemical Co., Ltd

Contact:0573-82613601

Address:Chemical Park, Jiaxing, Zhejiang, China

Relevant to this article

Asymmetric synthetic study of macrolactin analogues

Doi:10.1016/j.tet.2005.01.062
(2005)
Tandem Remote Csp³-H Activation/Csp³-Csp³ Cleavage in Unstrained Aliphatic Chains Assisted by Palladium(II)

Doi:10.1021/acs.organomet.8b00920
(2019)
Doi:10.1016/S0022-328X(00)90404-2
(1978)
Multidentate hybrid organotellurium ligands 1-(4-methoxyphenyltelluro)-2- [3-(6-methyl-2-pyridyl)propoxy]ethane (L¹) 2-methyl-6-{3-[2-({2-[3- (6-methyl-2-pyridyl)propoxy]ethyl}telluranyl)ethoxy]propyl}pyridine (L ²) and their metal c

Doi:10.1016/j.poly.2005.12.010
(2006)
Synthesis, Structure, Theoretical Studies, and Ligand Exchange Reactions of Monomeric, T-Shaped Arylpalladium(II) Halide Complexes with an Additional, Weak Agostic Interaction

Doi:10.1021/ja037928m
(2004)
Stereoselective synthesis of new classes of atropisomeric compounds through a tandem Michael reaction-azacyclization process. Part 2

Doi:10.1016/j.tetasy.2003.10.025
(2004)

Article Doi