Tetrahedron Letters p. 8571 - 8574 (1999)
Update date:2022-07-30
Topics:
Stephan, Elie
Olaru, Adina
Jaouen, Gerard
The methylthiodiphenylphosphine oxide carbanion 1a reacted with ketones in a two step process, the first stage being reversible. Methyl vinyl sulfides are formed only when the elimination step was rapid. When the second step occurred at a slow rate, the s
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