Synthesis of methyl vinyl sulfides: The role of boron trifluoride in promoting a Horner-Wittig type reaction

DOI: 10.1016/S0040-4039(99)01829-8

Source and publish data:

Tetrahedron Letters p. 8571 - 8574 (1999)

Update date:2022-07-30

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Authors:

Stephan, Elie

Olaru, Adina

Jaouen, Gerard

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Article abstract of DOI:10.1016/S0040-4039(99)01829-8

The methylthiodiphenylphosphine oxide carbanion 1a reacted with ketones in a two step process, the first stage being reversible. Methyl vinyl sulfides are formed only when the elimination step was rapid. When the second step occurred at a slow rate, the s

Full text of DOI:10.1016/S0040-4039(99)01829-8

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