Kinetic Facial Selectivity in Nucleophilic Displacements at Tetracoordinate Phosphorus: Kinetics and Stereochemistry in the Reaction of Sodium Ethoxide with O,S-Dimethyl Phenylphosphonothioate

DOI: 10.1021/ja00197a056

Source and publish data:

Journal of the American Chemical Society p. 5871 - 5879 (1989)

Update date:2022-08-04

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Authors:

DeBruin, Kenneth E.

Tang, Chen-lan W.

Johnson, David M.

Wilde, Ronnie L.

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Article abstract of DOI:10.1021/ja00197a056

The reaction of ethoxide ion with O,S-dimethyl phenylphosphonothioate (1a) proceeds with competitive displacements of the methylthio and methoxy ligands.Each displacement occurs with complete inversion of configuration.The two products, ethyl methyl pheny

Full text of DOI:10.1021/ja00197a056

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