Journal of Organic Chemistry p. 5589 - 5591 (1993)
Update date:2022-08-04
Topics:
Soederberg, Bjoern C.
Helton, E. Scott
Austin, Lucinda R.
Odens, Herman H.
Thermal reaction of N-arylamino-substituted Fischer chromium carbenes having a pendant 2-(1-alkenyl)substituent on the benzene ring affords either substituted indoles or quinolines, depending on starting material, via an intramolecular <2 + 2> cycloaddition forming a metallacyclobutane followed by metathesis to give indoles or β-elimination to give quinolines.
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