Biosynthesis of (+)-epicubenol

DOI: 10.1016/S0040-4039(00)73498-8

Source and publish data:

Tetrahedron Letters p. 5355 - 5358 (1994)

Update date:2022-08-02

Topics: Chiral Enantioselective Cyclization Biosynthesis Chemoenzymatic Isoprenoid Diterpene

Authors:

Cane, David E.

Tandon, Manish

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)73498-8

Incubation of [6-²H]FPP (14a) with epicubenol synthase isolated from Streptomyces sp. LL-B7 gave epicubenol (1c) labeled at D-9 as established by ²H NMR. These results confirm the involvement of a predicted 1,2-hydride shift in the mechanism of formation of 1.

Full text of DOI:10.1016/S0040-4039(00)73498-8

Products guided by the article

Product name:5-methyl-hex-4-enyl triphenyl phosphonium iodide

Cas No:67858-91-7

R&D Labs maybe for 67858-91-7

Beijing Harmony Chemical Co., Ltd.

Contact:86-010-84956928

Address:Room 207, Jin feng he B building, No 8 Xin Jie Kou Wai Street, Xi Cheng District, Beijing,PRC. 10008
ZiBO KuoDing Trade company Ltd

website:http://www.sdzbkd.com

Contact:86-13361591822

Address:GongQingTuan road
JiangXi Hong Run Chemical Co., Ltd

Contact:+86-0791-88521351

Address:XingHuo industrial zone in YongXiu county
Nanjing Ruizhi Industry & Technologh Co.，Ltd.

Contact:+86-25-86808110

Address:441-4-A5,NO.12 Longzang Avenue,Yuhuatai District,210039,Nanjing
Anhui Xinyuan Technology Co.,Ltd

Contact:0086-559-3515800

Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China

Relevant to this article

N-heterocyclic carbene adducts of cyclopalladated ferrocenylpyridazine: Synthesis, structural characterization, and application in α-arylation of ketones with aryl chlorides

Doi:10.1071/CH12035
(2012)
222. Inductivity and Bridging in 2-Bicyclo<2.2.2>octyl Cations. Polar Effects, Part II.

Doi:10.1002/hlca.19840670729
(1984)
Synthesis and characterization of highly-fluorinated colorless polyimides derived from 4,4′-((perfluoro-[1,1′-biphenyl]-4,4′-diyl)bis(oxy))bis(2,6-dimethylaniline) and aromatic dianhydrides

Doi:10.1016/j.polymer.2015.09.019
(2015)
Isolation and Stereochemistry of Optically Active Selenoximines

Doi:10.1246/bcsj.77.375
(2004)
Meta-Substituted benzamide oligomers that complex mono-, di- and tricarboxylates: Folding-induced selectivity and chirality

Doi:10.1039/c1ob06026k
(2011)
Doi:10.1016/S0040-4039(01)94761-6
(1978)

Article Doi