Biosynthesis of (+)-epicubenol

DOI: 10.1016/S0040-4039(00)73498-8

Source and publish data:

Tetrahedron Letters p. 5355 - 5358 (1994)

Update date:2022-08-02

Topics: Chiral Enantioselective Cyclization Biosynthesis Chemoenzymatic Isoprenoid Diterpene

Authors:

Cane, David E.

Tandon, Manish

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Article abstract of DOI:10.1016/S0040-4039(00)73498-8

Incubation of [6-²H]FPP (14a) with epicubenol synthase isolated from Streptomyces sp. LL-B7 gave epicubenol (1c) labeled at D-9 as established by ²H NMR. These results confirm the involvement of a predicted 1,2-hydride shift in the mechanism of formation of 1.

Full text of DOI:10.1016/S0040-4039(00)73498-8

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