Monatshefte fur Chemie p. 3 - 11 (1983)
Update date:2022-07-30
Topics:
Perkizas, George
Nikokavouras, John
Eight 9-benzylidene-N-methylacridan derivatives were synthesized and their chemiluminescence quantum yields on recation with NAOCl-H2O2 or O3 in N,N-dimethylformamide were plotted versus Hammett's "?" values.A good linear fit was obtained, the higher quantum yields being associated with negative "?" values.Two acridans did not fit in the plot and a novel treatment of chemiluminescence quenching is outlined to account for the discrepancy. - Keywords: Acridans; Chemiluminescence; Hammett; Quenching
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