Journal of Molecular Structure p. 143 - 148 (1998)
Update date:2022-08-04
Topics:
Van Camp, Mary Josepha
Morris, Shawn
Mudge, Annmarie
Points, Richard
Knight, Jodi B.
Schullery, Stephen E.
Scott, Ronald M.
The proton-transfer indicator reaction method is applied to the pentachlorophenol-triethylamine proton-transfer equilibrium K(PT) undergoing solvation by tetrahydropyran, 1,3-dioxane, and 1,4-dioxane in bulk cyclohexane. A predicted decrease in K(PT) occurs owing to hydrogen bonding solvation of the free phenol upon increasing ether concentration. However, the data unexpectedly suggest that hydrogen bonding solvation by the ethers to the proton of the proton-transfer adduct also occurs.
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