Tetrahedron Letters p. 9433 - 9434 (1994)
Update date:2022-07-30
Topics: Synthesis Lewis acid Reactions Carbonyl Compounds Regioselective Experimental Gallium
Han, Ying
Huang, Yao-Zeng
One-pot reactions of gallium powder, trimethylsilylpropargyl bromide, aldehydes or ketones in the presence of KI and LiCl show very high acetylenic selectivity and under the same conditions, trimethylsilylallyl bromide also exhibits very high selectivity
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