Stereochemical proof for front side deuteride attack via σ-sulfurane in the reductive desulfinylation of sulfoxides with lithium aluminum deuteride

DOI: 10.1016/S0040-4039(00)60611-1

Source and publish data:

Tetrahedron Letters p. 4043 - 4046 (1993)

Update date:2022-08-02

Topics:

Authors:

Sagae, Takahiro

Ogawa, Satoshi

Furukawa, Naomichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)60611-1

Stereochemical results obtained from the concomitant reduction and desulfinylation of 1-phenyl-2-pyridyl-2(p-tolysulfinyl)- and 1,2-diphenyl-2-phenylsulfinyl ethanols with lithium aluminum deuteride reveal that the reactions proceed stereospecifically via

Full text of DOI:10.1016/S0040-4039(00)60611-1

Products guided by the article

Product name:+/--erythro-2-deuterio-1,2-diphenylethanol

Cas No:6932-62-3

R&D Labs maybe for 6932-62-3

Shanghai Egoal Chemical Co.,Ltd

Contact:+86-21-50333091

Address:Yangming Garden Square 3,YangGao North Road 1188, Pudong New District, Shanghai
Amadis Chemical Co., Ltd.

website:http://www.amadischem.com

Contact:86-571-89925085

Address:Watts Cosine.No.166.Xiangmao Road.
Dalian Synco Chemical Co., Ltd.

Contact:+86-411-83635150

Address:Rm 1004, 24, Tangshan Street, Dalian
Zhengzhou Yuanli Biological Technology Co., Ltd.

Contact:+86-371-67897870/67897895

Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
Dongtai Xinyuan Chemical Co., Ltd.

Contact:+86-21-56733000

Address:404F, 99Nong No.117 Zhongtan Rd. Shanghai

Relevant to this article

Reactivity of the bridged-sulfide complex Pd₂Cl ₂(μ-S)(μ-dmpm)₂ toward electrophiles

Doi:10.1039/c1dt11961c
(2012)
Enantio- and diastereoselective synthesis of highly substituted acylcyclopropanes from homoaldol products by stereospecific homoallylic cyclization

Doi:10.1002/ejoc.200500283
(2005)
Synthesis and kinetic evaluation of 4-deoxy-4-phosphonomethyl-D- erythronate, the first hydrolytically stable and potent competitive inhibitor of ribose-5-phosphate isomerase

Doi:10.1016/j.tetlet.2004.03.004
(2004)
Novel diterpenelactones with anti-peptic ulcer activity from Croton sublyratus

Doi:10.1248/cpb.28.227
(1980)
Doi:10.1021/jo01164a007
(1948)
Positional specificity of Flavobacterium johnsoniae acetylxylan esterase and acetyl group migration on xylan main chain

Doi:10.1016/j.carbpol.2019.115783
(2020)

Article Doi