Tetrahedron Letters p. 4681 - 4684 (1990)
Update date:2022-08-04
Topics:
Barton, Derek H. R.
Jang, Doo Ok
Jaszberenyi, Joseph Cs.
Thiocarbonyl derivatives of secondary alcohols are readily reduced by diphenylsilane in a radical chain process at room temperature using triethylborane-air as an initiator. Primary alcohols react similarly at 80°. Comparison is made with the similar reactivity of tris(trimethylsilyl)silane.
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