Photoactivation of a Cobalt(III) Porphyrin by a Redox-active Axial Base-azaferrocene

DOI: 10.1039/c39920000662

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 662 - 663 (1992)

Update date:2022-07-30

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Authors:

Zakrzewski, Janusz

Giannotti, Charles

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Article abstract of DOI:10.1039/c39920000662

The cobalt(III) porphyrin, BF4 reacts with azaferrocene (AF) to give isolable complex BF4 which is light sensitive and undergoes photoreduction to CoTPP via photoinduced electron transfer from axial ligand AF.

Full text of DOI:10.1039/c39920000662

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