Tetrahedron Letters p. 3861 - 3864 (1987)
Update date:2022-07-30
Topics: Optical purity Product Isolation Reaction Conditions Analysis Substrate Preparation Selection of Enzyme Enzymatic Reaction
Gutman, Arie L.
Zuobi, Kheir
Boltansky, Aviv
Porcine pancreatic lipase in anhydrous organic solvents catalyses the lactonisation of a number of esters of γ-hydroxyacids in nearly quantitative yields.This enzymatic process was used for the highly stereoselective synthesis of (S)-(-)-γ-methylbutyrolactone, (R)-(+)-γ-methylbutyrolactone and of optically active γ-phenylbutyrolactone.
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