SYNTHESIS OF HOMOALLYL ALCOHOLS BY THE REACTION OF ?-ALLYLDICYCLOPENTADIENYLTITANIUM(III) WITH CARBONYL COMPOUNDS

DOI: 10.1016/0040-4039(81)80066-4

Source and publish data:

Tetrahedron Letters p. 243 - 246 (1981)

Update date:2022-08-03

Topics:

Authors:

Sato, Fumie

Iijima, Satoshi

Sato, Masao

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(81)80066-4

Reaction of ?-allyldicyclopentadienyltitanium(III) complexes, preformed or formed in situ, with aldehydes or ketones proceeds with regiospecificity, high stereoselectivity and chemospecificity, affording, under mild conditions, the corresponding homoallyl alcohols after hydrolysis in excellent yields.

Full text of DOI:10.1016/0040-4039(81)80066-4

Products guided by the article

Product name:3-ethyl-2-methylpent-4-en-2-ol

Cas No:70760-07-5

R&D Labs maybe for 70760-07-5

ShangHai Original Economy-Trade Develop Co.,Ltd.,

Contact:86-21-68552131

Address:shanghai
JenKem Technology Co., Ltd.

Contact:86-10-62983737; +86-10-51287608

Address:4/F Building C, 2 Shangdi Xinxi Road
Shanghai Hanshare Industry Co.,Ltd.

Contact:86 21 20960688

Address:RM902-903,Building E, Wanda Plaza,No.26,Zhoukang Road, Pudong District, Shanghai, China
Xi'an Costrong Pharmaceutical Co., Ltd.

Contact:029- 68576496

Address:Room 2004,Shuibao Building,No.190,South Erhuan Rd, Yanta District,Xi'an,Shaan Xi,China
Wuhan Shangrisyn chemicals Technology Co.,Ltd(expird)

Contact:+86-027-84466317 __ +86-15387123698

Address:wuhan - china

Relevant to this article

A facile highly regio- and stereoselective preparation of N-tosyl allylic amines from allylic alcohols and tosyl isocyanate via palladium(II)-catalyzed aminopalladation-β-heteroatom elimination

Doi:10.1021/ol006130u
(2000)
Efficient Kinetic Resolution of Sulfur-Stereogenic Sulfoximines by Exploiting Cp^XRh^III-Catalyzed C?H Functionalization

Doi:10.1002/anie.201904543
(2019)
Doi:10.1039/DT9790000609
()
Doi:10.1021/jo01333a025
(1979)
Radical Hydroarylation of Functionalized Olefins and Mechanistic Investigation of Photocatalytic Pyridyl Radical Reactions

Doi:10.1021/jacs.8b10238
(2018)
Structural studies of N-2-(6-picolyl)-N′-tolylthioureas

Doi:10.1023/A:1015688104995
(2002)

Article Doi