SYNTHESIS OF HOMOALLYL ALCOHOLS BY THE REACTION OF ?-ALLYLDICYCLOPENTADIENYLTITANIUM(III) WITH CARBONYL COMPOUNDS

DOI: 10.1016/0040-4039(81)80066-4

Source and publish data:

Tetrahedron Letters p. 243 - 246 (1981)

Update date:2022-08-03

Topics:

Authors:

Sato, Fumie

Iijima, Satoshi

Sato, Masao

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Article abstract of DOI:10.1016/0040-4039(81)80066-4

Reaction of ?-allyldicyclopentadienyltitanium(III) complexes, preformed or formed in situ, with aldehydes or ketones proceeds with regiospecificity, high stereoselectivity and chemospecificity, affording, under mild conditions, the corresponding homoallyl alcohols after hydrolysis in excellent yields.

Full text of DOI:10.1016/0040-4039(81)80066-4

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