SYNTHESIS OF HOMOALLYL ALCOHOLS BY THE REACTION OF ?-ALLYLDICYCLOPENTADIENYLTITANIUM(III) WITH CARBONYL COMPOUNDS

DOI: 10.1016/0040-4039(81)80066-4

Source and publish data:

Tetrahedron Letters p. 243 - 246 (1981)

Update date:2022-08-03

Topics:

Authors:

Sato, Fumie

Iijima, Satoshi

Sato, Masao

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(81)80066-4

Reaction of ?-allyldicyclopentadienyltitanium(III) complexes, preformed or formed in situ, with aldehydes or ketones proceeds with regiospecificity, high stereoselectivity and chemospecificity, affording, under mild conditions, the corresponding homoallyl alcohols after hydrolysis in excellent yields.

Full text of DOI:10.1016/0040-4039(81)80066-4

Products guided by the article

Product name:3-ethyl-2-methylpent-4-en-2-ol

Cas No:70760-07-5

R&D Labs maybe for 70760-07-5

Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
shijiazhuang shuanglian chemical industry co.,ltd

Contact:0311-82190302

Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway，Shijiazhuang City
Wuhan Kemi-Works Chemical Co., Ltd

website:http://www.kemiworks.com

Contact:86-27-85736489

Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
JIAXING SUNS INTERNATIONAL TRADE CO LTD

Contact:18367306858

Address:No.123,Huixin Avenue,Huimin Dist
NanJing KaiHeng Chemical CO., LTD.

Contact:+86-25-85768391

Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA

Relevant to this article

A facile highly regio- and stereoselective preparation of N-tosyl allylic amines from allylic alcohols and tosyl isocyanate via palladium(II)-catalyzed aminopalladation-β-heteroatom elimination

Doi:10.1021/ol006130u
(2000)
Efficient Kinetic Resolution of Sulfur-Stereogenic Sulfoximines by Exploiting Cp^XRh^III-Catalyzed C?H Functionalization

Doi:10.1002/anie.201904543
(2019)
Doi:10.1039/DT9790000609
()
Doi:10.1021/jo01333a025
(1979)
Radical Hydroarylation of Functionalized Olefins and Mechanistic Investigation of Photocatalytic Pyridyl Radical Reactions

Doi:10.1021/jacs.8b10238
(2018)
Structural studies of N-2-(6-picolyl)-N′-tolylthioureas

Doi:10.1023/A:1015688104995
(2002)

Article Doi