Chemical Communications p. 1020 - 1021 (2004)
Update date:2022-08-04
Topics:
Hill, Michael
Kehr, Gerald
Erker, Gerhard
Kataeva, Olga
Froehlich, Roland
The diphenyl-ansa-zirconocene complex 2 adds HB(C6F 5)2 at the C=C double bond of its pendent Cp-allyl functional group to yield 3. During 3 days at room temperature the -B(C 6F5)2 group takes part in an electrophilic substitution reaction at the adjacent Cp-ring to form 5 with formation of one equivalent of benzene. Complex 5 was characterized by X-ray diffraction.
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