
Tetrahedron p. 4359 - 4364 (1981)
Update date:2022-08-05
Topics:
Oppolzer
Battig
Hudlicky
The racemic sesquiterpenes isocomene I and β-isocomene 22 have been synthesized starting from 1,7-octadien-3-one 10 in a stereoselective manner. In the key step 12 → 13 (Scheme 5) the C-7, C-8-bond was formed by an intramolecular thermal ene reaction. Fur
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