Mechanistic Studies of the Reaction of 4-Substituted 1,2,4-Triazoline-3,5-diones with β-Dicarbonyl Compounds

DOI: 10.1021/jo01295a014

Source and publish data:

Journal of Organic Chemistry p. 1232 - 1239 (1980)

Update date:2022-08-05

Topics:

Authors:

Williams, Grady A.

Butler, George B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01295a014

4-Substituted 1,2,4-triazoline-3,5-diones were found to add to the α position of β-diketones and β-diketo esters, yielding both 1:1 and 2:1 adducts.The 1:1 adducts showed a dramatic stabilization of the enolic tautomer when compared to the original β-dica

Full text of DOI:10.1021/jo01295a014

Products guided by the article

Product name:2-(4-Phenyl-2H-1,2,4-triazoline-3,5-dionyl)-1,3-cyclohexanedione

Cas No:72708-72-6

R&D Labs maybe for 72708-72-6

Shanghai Korey Pharm Co.,Ltd.(expird)

Contact:021-61840961 021-61840962

Address:No.157,Zhuguang Rd, Qingpu, Shanghai, China
Chongqing Changfeng Chemical Co., Ltd.

website:http://www.changfengchem.com

Contact:+86-23-67896333

Address:30th Floor, Longhu Ziduxingzuo Building A, 1st Branch,YuSong Rd., Yubei District, Chongqing, China
Nanjing Raise Pharmatech Co., Ltd

website:http://www.raisechem.com

Contact:+86-25-58649566

Address:B381,No.606,Ningliu Road,Jiangbei New Area,Nanjing,Jiangsu Province,China
Zhangjiagang Jianing Import & Export Co.,Ltd.

Contact:086-512-55379012 13913607595

Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
Jiangyin Tenghua Import&Export Co.,Ltd.

Contact:+86-510-86263875

Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China

Relevant to this article

Optimization and anti-cancer properties of fluoromethylketones as covalent inhibitors for ubiquitin C-terminal hydrolase L1

Doi:10.3390/molecules26051227
(2021)
Reactivity of diaryliodine(III) triflates toward palladium(II) and platinum(II): Reactions of C(sp²)-I bonds to form arylmetal(IV) complexes; access to dialky(aryl)metal(IV), 1,4-benzenediyl-bridged platinum (IV); and triphenylplatinum(IV) species; and structural studies of platinum(IV) complexes

Doi:10.1021/om040023c
(2004)
Iron(III) Porphyrin Sulphate Complexes. Total Assignment of the Carbon-13 N.M.R. Spectrum

Doi:10.1039/c39800000455
(1980)
Complexes of (arylimido)molybdenum(V)

Doi:10.1021/ic50207a002
(1980)
Synthesis and characterization of antitumor-active platinum 2,2-dimethyl- 1,3-diaminopropane compounds. Crystal and molecular structure of (malonato)(2,2-dimethyl-1,3-diaminopropane)platinum(II)

Doi:10.1021/ic50208a011
(1980)
Lipophilic phosphonium-lanthanide compounds with magnetic, luminescent, and tumor targeting properties

Doi:10.1016/j.jinorgbio.2011.09.035
(2012)

Article Doi