Mechanistic Study of Thermal Z-E Isomerization of Azobenzenes by High-Pressure Kinetics

DOI: 10.1021/ja00382a026

Source and publish data:

Journal of the American Chemical Society p. 4900 - 4904 (1982)

Update date:2022-08-04

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Authors:

Asano, Tsutomu

Yano, Toshio

Okada, Toshio

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Article abstract of DOI:10.1021/ja00382a026

Pressure effects for the thermal Z-E isomerization of several azobenzenes were measured in various solvents.The activation volumes for 4-(dimethylamino)-4'-nitroazobenzene indicate that the reaction mechanism changes from inversion in n-hexane to rotation

Full text of DOI:10.1021/ja00382a026

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