Journal of the American Chemical Society p. 4900 - 4904 (1982)
Update date:2022-08-04
Topics:
Asano, Tsutomu
Yano, Toshio
Okada, Toshio
Pressure effects for the thermal Z-E isomerization of several azobenzenes were measured in various solvents.The activation volumes for 4-(dimethylamino)-4'-nitroazobenzene indicate that the reaction mechanism changes from inversion in n-hexane to rotation
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