Journal of Fluorine Chemistry p. 53 - 73 (1991)
Update date:2022-08-05
Topics:
Meinert, H.
Fackler, R.
Mader, J.
Reuter, P.
Roehlke, W.
Electrochemical fluorination (ECF) of α,ω-dimorpholino- and dipiperidino-alkanes of different chain length (n = 1-6) and of morpholinocyclohexene gave the perfluoro derivatives in yields up to 45percent.By ring contractions, fragmentations and rearrangements several side products were obtained.Conclusions on the mechanism of ECF, based on a sterical model, were drawn.
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