Synthesis of o-Deuterio- and o-Halogeno-acetophenones via Oxidation of η2-(2-Acetylphenyl)tetracarbonylmanganese Derivatives and the Determination of a Primary Kinetic Isotope Effect in ortho-Metallation of Acetophenones

DOI: 10.1039/c39860000012

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 12 - 13 (1986)

Update date:2022-08-04

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Authors:

Gommans, Louie H. P.

Main, Lyndsay

Nicholson, Brian K.

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Article abstract of DOI:10.1039/c39860000012

2'-Deuterioacetophenone and 2'-deuterio-3',4',5'-trimethoxyacetophenone are obtained by reaction of the corresponding η²-(2-acetylphenyl)tetracarbonylmanganese compounds with cerium(IV) ammonium nitrate in CD3CO2D while 2'-iodo- and 2'-bromo-3'

Full text of DOI:10.1039/c39860000012

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