FACILE PREPARATION OF 2,6-DIMETHYL-2,6-TETRAHYDROPYRANCARBOLACTONE, A VERSATILE INTERMEDIATE FOR THE SYNTHESES OF (+/-)-FRONTALIN, (+/-)-CINENIC ACID, AND (+/-)-LINALOYL OXIDE

DOI: 10.1016/S0040-4039(00)81983-8

Source and publish data:

Tetrahedron Letters p. 2567 - 2570 (1983)

Update date:2022-07-30

Topics:

Authors:

Utaka, Masanori

Makino, Hiroshi

Oota, Yukito

Tsuboi, Sadao

Takeda, Akira

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Article abstract of DOI:10.1016/S0040-4039(00)81983-8

2,6-Dimethylcyclohexanone has been converted via its 2,6-dihydroxy derivative by base-catalyzed oxygenation to 2,6-dimethyl-2,6-tetrahydropyrancarbolactone which can be used as a key intermediate for the syntheses of the title natural products in racemic forms.

Full text of DOI:10.1016/S0040-4039(00)81983-8

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