SYNTHESIS OF 2-AMINO-2-DEOXY-α-D-GLUCOPYRANOSYL-β-D-FRUCTOFURANOSIDE (2-AMINO-2-DEOXY-SUCROSE)

Article abstract of DOI:10.1246/cl.1980.183

2-Amino-2-deoxy-α-D-glucopyranosyl β-D-fructofuranoside (2-amino-2-deoxy-sucrose) was synthesized by condensation of 3,4,6-tri-O-acetyl-2-(2,4-dinitroanilino)-2-deoxy-α-D-glucopyranosyl bromide and 1,3,4,6-tetra-O-benzyl-D-fructofuranose with the aid of silver perchlorate and tribenzylamine in benzene, followed by removal of protecting groups.