Chemistry Letters p. 1001 - 1004 (1980)
Update date:2022-09-26
Topics:
Kitagawa, Isao
Shibuya, Hirotaka
Fujioka, Hiromichi
Kajiwara, Akiharu
Tsujii, Shinji
Yamamoto, Yoshio
A chiral 1,1,3-trimethylcyclohexane derivative (12), which is a potent key building block for synthesis of ent-taxane-type diterpenoids, has been prepared from d-camphor (2) through a conversion pathway which involves a novel ring enlargement reaction of a 1,1,2-trimethylcyclopentane derivative (3).
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