Bulletin of the Chemical Society of Japan p. 3599 - 3600 (1981)
Update date:2022-08-05
Topics:
Nakajima, Riichiro
Morita, Kazuhiro
Hara, Tadashi
The hydrogenolysis and dimerization of iodoalkanes were catalyzed by Pd in the presence of an appropriate reducing agent.Hydrazine was found to be effective for the coupling of 1-iodoeicosane to give tetracontane, C40H82, in a 74 percent yield.The yield of the coupling product decreased with the decrease of the number of the carbon atoms in the 1-iodoalkanes.Both alkylhydrazines and alkenes were shown not to take part in the reaction as a reaction intermediate.
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