Diazoalkane complexes and Related Compounds from Reactions of Dinitrogen Complexes of Tungsten and Molybdenum with gem-Dibromides, and from Condensation of Hydrazido(2-)-complexes with Aldehydes

DOI: 10.1039/DT9800000771

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 771 - 775 (1980)

Update date:2022-08-05

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Authors:

Ben-Shoshan, Raphael

Chatt, Joseph

Leigh, Jeffery, G.

Hussain, Wasif

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Article abstract of DOI:10.1039/DT9800000771

The reactions of trans- with gem-dibromides lead to new diazoalkane complexes.These do not react with protonic acids, but the unique diazoalkane carbons are attacked by nucleophiles, such as LiMe, to yield diazenido-complexes, som

Full text of DOI:10.1039/DT9800000771

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