Reversible π-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

DOI: 10.1016/j.inoche.2003.12.032

Source and publish data:

Inorganic Chemistry Communications p. 443 - 446 (2004)

Update date:2022-08-05

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Authors:

Thapper, Anders

Sparr, Emma

Johnson, Brian F.G.

Lewis, Jack

Raithby, Paul R.

Nordlander, Ebbe

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Article abstract of DOI:10.1016/j.inoche.2003.12.032

The triallylphosphine-substituted clusters [Ru₃(CO) ₁₁{P(CH₂CH=CH₂)₃}], [Ru ₃(CO)₁₀{P(CH₂CH=CH₂) ₃}₂] and [Ru₃(CO)₁₀{σ;π- CH₂=CHCH₂P(CH₂CH=CH₂)₂}] have been prepared; reaction of [Ru₃(CO)₁₀{σ;π- CH₂=CHCH₂P(CH₂CH=CH₂)₂}] with phosphines/phosphites leads to cleavage of the Ru-allyl π-bond and formation of [Ru₃(CO)₁₁{P(CH₂CH=CH ₂)₃}(PR₃)].

Full text of DOI:10.1016/j.inoche.2003.12.032

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