(Trimethylsilyl)allenes as Propargylic Anion Equivalents: Synthesis of Homopropargylic Alcohols and Ethers

DOI: 10.1021/jo01307a044

Source and publish data:

Journal of Organic Chemistry p. 3925 - 3927 (1980)

Update date:2022-08-03

Topics:

Authors:

Danheiser, Rick L.

Carini, David J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01307a044

(Trimethylsilyl)allenes react with ketones, aldehydes, and acetals in the presence of titanium tetrachloride to yield homopropargylic alcohols and ethers.

Full text of DOI:10.1021/jo01307a044

Products guided by the article

Product name:1-(4-methyl-2-pentynyl)-1-cyclohexanol

Cas No:74552-19-5

R&D Labs maybe for 74552-19-5

Zouping Fuhai Technology Development Co., Ltd.

Contact:+0532-86934525 18660293207

Address:jiuhu town industrial park Zouping County,bingzhou Provincejiuhu town industrial park
Shanghai Maxchemco Chemical Industry Co., Ltd.

Contact:(86)21-51079223

Address:No.1305-8, B241, the Ecust Park, Huajing Road, Xuhui District, Shanghai
Changzhou Hopschain Chemical Co.,Ltd

website:http://www.hopschem.cn/products.html

Contact:86-519-85528066

Address:Room 710, Unit A, Xingbei Development Mansion, Tongjiang Road, Changzhou City,213000, China
Ningbo J&S Botanics Inc.

Contact:86-574-26865651

Address:529 YuanBaoShan Road, Beilun District
Chengdu Herbpurify Co., Ltd

website:http://www.herbpurify.com

Contact:0086-028-85249238

Address:Room709-C1,Incubator Building, Tianfu Life Science Park No.88,Keyuan Road,Gaoxin district,Chengdu City,Sichuan Prov,China

Relevant to this article

Modifications of the C6-substituent of penicillin sulfones with the goal of improving inhibitor recognition and efficacy

Doi:10.1016/j.bmcl.2010.10.134
(2011)
Stereocontrolled syntheses of O-glycans of core class 2 with a linear tetrameric lactosamine chain and with three lactosamine branches

Doi:10.1016/S0008-6215(96)90116-0
(1996)
C6 modification of the pyridinone core of thrombin inhibitor L-374,087 as a means of enhancing its oral absorption

Doi:10.1016/S0960-894X(98)00297-2
(1998)
Synthesis and characterization of copper-ibuprofenate complexes with 2,2′-bipyridine and 1,10-phenanthrolines and their hydrolytic activities in phosphate diester cleavage

Doi:10.1016/0277-5387(96)00214-8
(1997)
The first enantioselective synthesis of optically pure (R)- and (S)- 5,5''-dihydroxy-4',4''',7,7''-tetramethoxy-8,8''- biflavone and the reconfirmation of their absolute configuration

Doi:10.1016/S0040-4039(96)02475-6
(1997)
Doi:10.1021/jo01256a089
(1969)

Article Doi