(Trimethylsilyl)allenes as Propargylic Anion Equivalents: Synthesis of Homopropargylic Alcohols and Ethers

DOI: 10.1021/jo01307a044

Source and publish data:

Journal of Organic Chemistry p. 3925 - 3927 (1980)

Update date:2022-08-03

Topics:

Authors:

Danheiser, Rick L.

Carini, David J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01307a044

(Trimethylsilyl)allenes react with ketones, aldehydes, and acetals in the presence of titanium tetrachloride to yield homopropargylic alcohols and ethers.

Full text of DOI:10.1021/jo01307a044

Products guided by the article

Product name:1-(4-methyl-2-pentynyl)-1-cyclohexanol

Cas No:74552-19-5

R&D Labs maybe for 74552-19-5

Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd

Contact:+86-771-2311266

Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
CHENGDU CHENLV HERB CO.,LTD

Contact:+86-28-88523492

Address:714rooms of Time Square, Pujiang County
Hubei Vanz Pharm Co.,Ltd

website:http://www.vanzpharm.com/en/index.html

Contact:86-27-84492310

Address:FANHU INDUSTRY PARK
Shijiazhuang Haotian Chemical Co., Ltd.

Contact:86-311-85044374

Address:293 Donggang Road
Suqian Ruixing Chemical Co., Ltd.

Contact:+86-527-80805666（总机）;84836008(销售)

Address:3 Jingsilu, Zone north, Hubin Xincheng Development Park, Suqian, China

Relevant to this article

Modifications of the C6-substituent of penicillin sulfones with the goal of improving inhibitor recognition and efficacy

Doi:10.1016/j.bmcl.2010.10.134
(2011)
Stereocontrolled syntheses of O-glycans of core class 2 with a linear tetrameric lactosamine chain and with three lactosamine branches

Doi:10.1016/S0008-6215(96)90116-0
(1996)
C6 modification of the pyridinone core of thrombin inhibitor L-374,087 as a means of enhancing its oral absorption

Doi:10.1016/S0960-894X(98)00297-2
(1998)
Synthesis and characterization of copper-ibuprofenate complexes with 2,2′-bipyridine and 1,10-phenanthrolines and their hydrolytic activities in phosphate diester cleavage

Doi:10.1016/0277-5387(96)00214-8
(1997)
The first enantioselective synthesis of optically pure (R)- and (S)- 5,5''-dihydroxy-4',4''',7,7''-tetramethoxy-8,8''- biflavone and the reconfirmation of their absolute configuration

Doi:10.1016/S0040-4039(96)02475-6
(1997)
Doi:10.1021/jo01256a089
(1969)

Article Doi