(Trimethylsilyl)allenes as Propargylic Anion Equivalents: Synthesis of Homopropargylic Alcohols and Ethers

DOI: 10.1021/jo01307a044

Source and publish data:

Journal of Organic Chemistry p. 3925 - 3927 (1980)

Update date:2022-08-03

Topics:

Authors:

Danheiser, Rick L.

Carini, David J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01307a044

(Trimethylsilyl)allenes react with ketones, aldehydes, and acetals in the presence of titanium tetrachloride to yield homopropargylic alcohols and ethers.

Full text of DOI:10.1021/jo01307a044

Products guided by the article

Product name:1-(4-methyl-2-pentynyl)-1-cyclohexanol

Cas No:74552-19-5

R&D Labs maybe for 74552-19-5

SEA BRGIHT INDUSTRY CO.,LIMITED

Contact:0086 755 8622 3990

Address:Rm 17B3,GuangCaiXinTianDi Bldg,GuiMiao Rd,NanShan District,Shenzhen,China
SINO GREAT ENTERPRISE LTD.

Contact:+86-731-84427351

Address:154 JIANXIANG SOUTH ROAD
Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
Guangzhou Chemical Reagent Factory

Contact:+86-20-8435 9820 or 8435 7345

Address:Southern Guangzhou, Guangdong, China
SHANGHAI ARCADIA BIOTECHNOLOGY LTD.

Contact:+86-21-61353236

Address:SUITE 901, BUILDING WENSLI, 1378 LU JIA BANG RD, SHANGAHI 200011, P.R.CHINA

Relevant to this article

Modifications of the C6-substituent of penicillin sulfones with the goal of improving inhibitor recognition and efficacy

Doi:10.1016/j.bmcl.2010.10.134
(2011)
Stereocontrolled syntheses of O-glycans of core class 2 with a linear tetrameric lactosamine chain and with three lactosamine branches

Doi:10.1016/S0008-6215(96)90116-0
(1996)
C6 modification of the pyridinone core of thrombin inhibitor L-374,087 as a means of enhancing its oral absorption

Doi:10.1016/S0960-894X(98)00297-2
(1998)
Synthesis and characterization of copper-ibuprofenate complexes with 2,2′-bipyridine and 1,10-phenanthrolines and their hydrolytic activities in phosphate diester cleavage

Doi:10.1016/0277-5387(96)00214-8
(1997)
The first enantioselective synthesis of optically pure (R)- and (S)- 5,5''-dihydroxy-4',4''',7,7''-tetramethoxy-8,8''- biflavone and the reconfirmation of their absolute configuration

Doi:10.1016/S0040-4039(96)02475-6
(1997)
Doi:10.1021/jo01256a089
(1969)

Article Doi