Journal of Organic Chemistry p. 3989 - 3993 (1980)
Update date:2022-07-29
Topics:
Goldsmith, David J.
John, Thottathil K.
Kwong, Cecil D.
Painter, George R.
The preparation of three trichothecane-like compounds, olefin 9 and epoxides 10 and 23, is reported.Subjection of 9 to conditions of acid-catalyzed rearrangement followed by hydrogenation leads to (+/-)-aplysin.The anti epoxide 10 also undergoes rearrangement but with migration of the aryl group rather than the pyranyl oxygen to give 26.Syn epoxide 23 does not undergo skeletal rearrangement.Hydrogenation of olefin 9 affords (+/-)-filiformin.
View MoreTianjin SPHINX SCIENTIFIC LAB.
Contact:+86-022-66211289
Address:Tianda high-tech Park. No.80,the 4th Avenue
Shanghai Longjin Metallic Material Co., Ltd.
website:http://www.shlongjin.cn/
Contact:021-56517503,56502257
Address:No.16, Lane 555, Chengyin Road, Shanghai
Taizhou volsen chemical Co., Ltd
website:http://www.volsenchem.com
Contact:+86-576-88869393
Address:Jiaojiang District, Taizhou, Zhejiang, China.
KAIYUAN CHEMICAL COMPANY LIMITED.
website:http://www.kaiyuanchem.com
Contact:+86-22-59891255/66/77
Address:B-2205, Kuangshi International Building, Yingbin Road, XiangLuo Bay Business District, Binhai New area, Tianjin, China.
HANGZHOU EVC CHEMICAL CO.,LTD.(expird)
Contact:+86-571-88296056
Address:Room#3001,Zhejiang Chemical Market,No.10,Road Shenban,Hangzhou,Zhejiang,China
Doi:10.1007/BF00561344
(1980)Doi:10.1016/S0040-4039(00)71450-X
(1980)Doi:10.1016/0039-128X(80)90141-5
(1980)Doi:10.1021/ja01285a011
(1937)Doi:10.1021/ja01627a062
(1955)Doi:10.1021/jo01069a509
(1961)