Dimerisation of a Diplatinum to a Tetraplatinum Complex during Catalysis of the Water Gas Shift Reaction: the X-Ray Crystal Structure of 4(μ2-CO)2(μ2-Ph2PCH2PPh2)32PCH2P(:O)Ph2>>

DOI: 10.1039/c39820000198

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 198 - 200 (1982)

Update date:2022-08-02

Topics:

Authors:

Frew, Aileen A.

Hill, Ross H.

Manojlovic-Muir, Ljubica

Muir, Kenneth W.

Puddephatt, Richard J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39820000198

The binuclear complex , dppm = Ph2PCH2PPh2, is an active catalyst precursor for the water gas shift reaction, especially at low pressures of carbon monoxide; the catalytic solutions are shown to contain cluster complexes such as the tetranuclear (Pt4(μ-CO)2(μ-dppm)3>, whose 'butterfly' structure has been determined by X-ray crystallography.

Full text of DOI:10.1039/c39820000198

Products guided by the article

Product name:C₅₁H₄₅OP₄Pt₂⁽¹⁺⁾

Cas No:74587-81-8

R&D Labs maybe for 74587-81-8

Zhengzhou Yuanli Biological Technology Co., Ltd.

Contact:+86-371-67897870/67897895

Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD

Contact:+86-553-3836920

Address:7/F NO.82 LAODONG ROAD WUHU CHINA
Jinan Jianfeng Chemical Co., Ltd

Contact:0086-531-88110457

Address:sales01(-a-t-)pharmachemm{dot}c+o+m
QINGDAO TAOSIGN INTERNATIONAL TRADE CO.,LIMITED

Contact:+86-0532-82683616

Address:RM1402, Doublestar Seacoase 7#, No. 5 Guizhou Road, Qingdao, Shandong, China
Xi'an North Information Industry Co., Ltd. Weilv Chemical Department

Contact:+86-29-88156413

Address:Jixiang Road 99 Xi'an Shaanxi Province

Relevant to this article

O-ACYLATED FLAVONOID GLYCOSIDES FROM THE NEEDLES OF Picea obovata II. 3''- and 6''-ISOMERS OF p-COUMAROYLASTRAGALIN

Doi:10.1007/BF00638772
(1980)
A simple and efficient radical reduction using water-soluble radical initiator and hypophosphorous acid in aqueous alcohol

Doi:10.1016/j.tetlet.2004.09.130
(2004)
A Nitrogen Analogue of Deltic Acid

Doi:10.1039/c39800000223
(1980)
The synthesis of derivatives of 3-amino-2,3-dideoxy-2-fluoro-D-altrose

Doi:10.1016/S0008-6215(00)85375-6
(1980)
Doi:10.1021/jo01278a006
(1967)
Multichannel Reaction of α-Bromoenones with 1,2-Diamines: Synthesis of 1,4-Diazabicyclo[4.1.0]hept-4-enes by Reaction with N-Unsubstituted 1,2-Diamines

Doi:10.1002/ejoc.201501584
(2016)

Article Doi