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THE INTER-AND INTRAMOLECULAR ADDITION OF AROMATIC KETONE TRIPLETS TO QUADRICYCLENES. COMPARISON WITH THE CORRESPONDING REACTIVITIES OF NORBORNADIENE, METHYLENENORBORNENE,METHYLENENORBORNANE AND NORBORNENE.

DOI: 10.1016/0040-4020(80)87008-6

Source and publish data:

Tetrahedron p. 397 - 409 (1980)

Update date:2022-08-04

Topics:

Authors:

Barwise, A. J. G.Barwise, A. J. G.

Gorman, A. A.Gorman, A. A.

Leyland, R. L.Leyland, R. L.

Parekh, C. T.Parekh, C. T.

Smith, P. G.Smith, P. G.

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Article abstract of DOI:10.1016/0040-4020(80)87008-6

Irradiation of acetophenone or benzophenone in the presence of norbornadiene or quadricyclene gives 1: 1-adducts.These arise via reaction of the ketone triplet with the quadricyclene.Similar reactivity is exhibited in an intramolecular sense by 7-phenacyl

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Full text of DOI:10.1016/0040-4020(80)87008-6

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