THE INTER-AND INTRAMOLECULAR ADDITION OF AROMATIC KETONE TRIPLETS TO QUADRICYCLENES. COMPARISON WITH THE CORRESPONDING REACTIVITIES OF NORBORNADIENE, METHYLENENORBORNENE,METHYLENENORBORNANE AND NORBORNENE.

DOI: 10.1016/0040-4020(80)87008-6

Source and publish data:

Tetrahedron p. 397 - 409 (1980)

Update date:2022-08-04

Topics:

Authors:

Barwise, A. J. G.

Gorman, A. A.

Leyland, R. L.

Parekh, C. T.

Smith, P. G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(80)87008-6

Irradiation of acetophenone or benzophenone in the presence of norbornadiene or quadricyclene gives 1: 1-adducts.These arise via reaction of the ketone triplet with the quadricyclene.Similar reactivity is exhibited in an intramolecular sense by 7-phenacyl

Full text of DOI:10.1016/0040-4020(80)87008-6

Products guided by the article

Product name:C₁₅H₁₄O

Cas No:74597-13-0

R&D Labs maybe for 74597-13-0

Shanghai united Scientific Co.,Ltd.

Contact:+86-21-53535353

Address:28F No.900 huaihai Road Shanghai China
SPRING CHEMICAL INDUSTRY CO.,LTD

Contact:86-187-66672125

Address:linchi industry park.zouping
Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China
Zhangjiagang Jianing Import & Export Co.,Ltd.

Contact:086-512-55379012 13913607595

Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
FREEBARQUE DEVELOPMENT GROUP LIMITED

Contact:+86(0)10-5109 5335 or 5109 5345

Address:Room602,Block1-B,LINGDI OFFICE,NO.13 BEIYUAN ROAD

Relevant to this article

Metal- and Base-Free Room-Temperature Amination of Organoboronic Acids with N-Alkyl Hydroxylamines

Doi:10.1002/anie.201802782
(2018)
An enantiodirected cyclopentenone annulation. Synthesis of a useful building block for condensed cyclopentanoid natural products

Doi:10.1021/ja00537a059
(1980)
A regiospecific synthesis of anthracyclinones

Doi:10.1016/S0040-4039(01)83772-2
(1977)
Enantioselective carbonyl-ene reaction on BINOLate/titanium catalyst encapsulated in magnetic nanoreactors

Doi:10.1039/c2cc17950d
(2012)
Doi:10.1021/jo00400a047
(1978)
Synthesis of 2-substituted 2,6-dihydro-3-hydroxy-7H-pyrazolo[4,3-d]pyrimidin-7-ones

Doi:10.1248/cpb.31.1228
(1983)

Article Doi