α-Nitro Ketones. 3. Stereochemistry of the Nitration of 1-Acetoxycyclohexenes: Synthesis of 2-Nitrocyclohexanones

DOI: 10.1021/jo00328a019

Source and publish data:

Journal of Organic Chemistry p. 3082 - 3087 (1981)

Update date:2022-08-04

Topics:

Authors:

Oezbal, Hadi

Zajac, Walter W.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00328a019

The nitration of enol acetates of substituted cyclohexanones in acetic anhydride at 15 deg C with concentrated nitric acid is a kinetically controlled process which can lead to cis-trans-substituted 2-nitrocyclohexanones in very good yields.The stereochem

Full text of DOI:10.1021/jo00328a019

Products guided by the article

Product name:cis-2-nitro-4-isopropylcyclohexanone

Cas No:74609-71-5

R&D Labs maybe for 74609-71-5

Shenzhen JYMed Technology Co.,Ltd.

website:http://www.jymedtech.com

Contact:+86-755-26612112

Address:1#8,9/F, Biomedicine innovation Industrial Park, No.14, Jinhui Road, Pingshan Sistrict, Shenzhen, China
Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.
HUNAN OUYA BIOLOGICAL CO.,LTD

Contact:+8613400661290

Address:No 908,Kangwan Rd, Liuyang Economic
SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD

website:http://www.jinjingroup.com

Contact:86-574-13989382828

Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China
Luzhou North Chemical Co., Ltd.

Contact:+86-830-2796784；+86-830-2796776

Address:Gaoba, Longmatan District, Luzhou, Sichuan Province

Relevant to this article

Thrombin inhibitors. 3. Carboxyl-containing amide derivatives of N alpha-substituted L-arginine.

Doi:10.1021/jm00186a003
(1980)
Formation of cyclic carbonates in the reactions of 1,2-glycols with oxalyl chloride

Doi:10.1248/cpb.41.408
(1993)
Radical addition reaction of brominated active methylene compounds to enol ethers using 2,2'-azobis(2,4-dimethyl-4-methoxyvaleronitrile) (V-70) as an initiator

Doi:10.1021/jo981900p
(1999)
HYDRIDE REDUCTION OF THE CATION <(η⁵-C5H5)Fe(Ph2PCH2CH2PPh2)CO>PF6; FORMATION OF (η⁵-C5H5)FeH(CO)(Ph2PCH2CH2PPh2) AND ELIMINATION OF H2 FROM <(η⁵-C5H5)FeH(CO)>2(Ph2PCH2CH2PPh2)

Doi:10.1016/S0022-328X(00)98519-X
(1983)
Olefin Metathesis-Transannular Ene Sequence. A Method for the Stereocontrolled Synthesis of trans-Decalin Derivatives. 1. Total Synthesis of (+/-)-Calameon

Doi:10.1021/jo01290a039
(1980)
New synthetic routes to allylic germatranes

Doi:10.1016/j.jorganchem.2004.05.011
(2004)

Article Doi