α-Nitro Ketones. 3. Stereochemistry of the Nitration of 1-Acetoxycyclohexenes: Synthesis of 2-Nitrocyclohexanones

DOI: 10.1021/jo00328a019

Source and publish data:

Journal of Organic Chemistry p. 3082 - 3087 (1981)

Update date:2022-08-04

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Authors:

Oezbal, Hadi

Zajac, Walter W.

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Article abstract of DOI:10.1021/jo00328a019

The nitration of enol acetates of substituted cyclohexanones in acetic anhydride at 15 deg C with concentrated nitric acid is a kinetically controlled process which can lead to cis-trans-substituted 2-nitrocyclohexanones in very good yields.The stereochem

Full text of DOI:10.1021/jo00328a019

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