A NEW SYNTHETIC PROCEDURE FOR THE CONVENIENT PREPARATION OF THIOCARBAMOYL CHLORIDES AND THE NOVEL BIS-THIOCARBAMOYL CHLORIDES

Article abstract of DOI:10.1016/0040-4020(80)80032-9

Treatment of N-silylamines with excess thiophosgene affords thiocarbamoyl chlorides in good yields and excellent purity.This method was also suitable for preparing the first bis-thiocarbamoyl chlorides from N,N'-bis(trimethylsilyl)-diamines.Bis-thiocarbam