THE METHYOXYMERCURATION OF A 6-DEOXYHEX-5-ENOPYRANOSIDE DERIVATIVE AND REACTIONS OF THE PRODUCTS

DOI: 10.1016/S0008-6215(00)85702-X

Source and publish data:

Carbohydrate Research p. 263 - 272 (1980)

Update date:2022-08-05

Topics: TLC analysis Yield NMR spectroscopy Derivative Reaction Conditions

Authors:

Ferrier, Robert J.

Prasit, Petpiboon

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Article abstract of DOI:10.1016/S0008-6215(00)85702-X

Methoxymercuration of methyl 3,4-di-O-benzoyl-6-deoxy-2-O-toluene-p-sulphonyl-α-D-xylo-hex-5-enopyranoside (5) at room temperature with mercury(II) acetate afforded the direct product of addition (8) with mercury bonded to the exocyclic carbon atom.Acetyl

Full text of DOI:10.1016/S0008-6215(00)85702-X

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Product name:1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1,5-di-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hex-5-enose aldehydrol

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