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Synthesis of (+/-)-4-Deoxypodophyllotoxin, (+/-)-Podophyllotoxin and (+/-)-Epipodophyllotoxin

DOI: 10.1039/P19930002541

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2541 - 2548 (1993)

Update date:2022-08-04

Topics:

Authors:

Jones David W.Jones David W.

Thompson, Adrian M.Thompson, Adrian M.

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Article abstract of DOI:10.1039/P19930002541

6,7-Methylenedioxy-1-(3',4',5'-trimethoxyphenyl)-2-benzopyran-3-one 1 and dimethyl fumarate in acetonitrile give mostly the C-2 exo-CO2Me adduct 4 which is transformed in four steps into epipodophyllotoxin 10a.Attempted addition of dimethyl maleate to 1 p

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Cas No:75171-59-4

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