THE STRUCTURES OF FOUR REACTION PRODUCTS OF 1,2,2a,3,4,5-HEXAHYDROPYRROLOCARBAZOLE WITH p-CHLOROBENZENESULPHONYL AZIDE

Article abstract of DOI:10.1107/S0567740880007352

The crystal structures of 12-(p-chlorophenylsulphonylamino)-6,7,10,11-tetrahydroazocino<1,2-α>indol-8(9H)-one, C20H19ClN2O3S (I) 1, 2050 reflexions, R_w = 0.045>, 14-(p-chlorophenyl)-8-(-p-chlorophenylsulphonylamino)-13-oxa-14-thia-1,15-diazapentacyclo<10.4.2.0^{2,7_.08,16_.012,16}>octadeca-2,4,6,14-tetraene S-oxide, C26H23Cl2N3O4S2 (II) w = 0.054>, 6-(p-chlorophenylsulphonylamino)-2,2a,3,4,5,6-hexahydro-2a,6-methano-1H-azeto<1,2-α><1>benzazocin-12-one, C20H19ClN2O3S (III) w = 0.044>, and 8-(p-chlorophenylsulphonylamino)-4-hydroxyimino-1,2,3,4,5,6,7,8-octahydro-1,8-methano<1>benzazecin-13-one pyridine solvate, C20H20ClN3O4S*C5H5N (IV) w = 0.057> have been determined.