Elimination and Addition Reactions. 36. Acceleration of Nucleophilic Eliminative Ring Fission by Bond Strain

DOI: 10.1021/ja00547a011

Source and publish data:

Journal of the American Chemical Society p. 7888 - 7892 (1980)

Update date:2022-08-05

Topics: Addition reaction Elimination Reaction nucleophilic Acceleration

Authors:

Palmer, Robert J.

Stirling, Charles J. M.

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Article abstract of DOI:10.1021/ja00547a011

Rates of eliminative ring fission of cyclic ethers bearing carbanion stabilizing groups have been measured with a view to assessing the contribution of ring strain to the ease of cleavage of bonds in elimination reactions. (Ethylsulfonylmethyl)oxiran (4)

Full text of DOI:10.1021/ja00547a011

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