High Periselectivity of 2-Oxyallyl Cations: Kinetic Evidence of the Cyclocoupling Reaction and Its Mechanistic Aspects

DOI: 10.1021/jo00316a010

Source and publish data:

Journal of Organic Chemistry p. 526 - 531 (1981)

Update date:2022-08-04

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Authors:

Ishizu, Takashi

Mori, Masato

Kanematsu, Ken

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Article abstract of DOI:10.1021/jo00316a010

The 2-oxyallyl cation prepared from 7 and Fe2(CO)9 shows high periselectivity in reactions with tropones and 6-(dimethylamino)fulvene, losing dimethylamine, to give the formally <2_?(3C)+8_?> and <2_?(3C)+6_?> adduc

Full text of DOI:10.1021/jo00316a010

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