High Periselectivity of 2-Oxyallyl Cations: Kinetic Evidence of the Cyclocoupling Reaction and Its Mechanistic Aspects

DOI: 10.1021/jo00316a010

Source and publish data:

Journal of Organic Chemistry p. 526 - 531 (1981)

Update date:2022-08-04

Topics:

Authors:

Ishizu, Takashi

Mori, Masato

Kanematsu, Ken

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00316a010

The 2-oxyallyl cation prepared from 7 and Fe2(CO)9 shows high periselectivity in reactions with tropones and 6-(dimethylamino)fulvene, losing dimethylamine, to give the formally <2_?(3C)+8_?> and <2_?(3C)+6_?> adduc

Full text of DOI:10.1021/jo00316a010

Products guided by the article

Product name:1,5-di-n-butyl-6,7-diphenyl-2,2,4,4-tetramethylbicyclo<3.2.1>oct-6-ene-3,8-dione

Cas No:75919-01-6

R&D Labs maybe for 75919-01-6

Ningbo Distant Chemicals Co.,Ltd

Contact:86-574-27862490,27862438

Address:5F-3,#54 DaShaNi street,Ningbo,CHINA
Nanyang Tianhua pharmaceutical Co.,Ltd.

Contact:+8618639816203

Address:Longsheng Industrial Park
TLS PHARMACEUTICAL CO.,LTD

Contact:0833-5590788/5590338/5590055

Address:Victory in the town of Red Star Village,Mount Emei City,industrial concentration area storage processing logistics parkpark
Yancheng Creator Chemical Co., Ltd

Contact:0086-515-88710008 88710068 88710858 88710868

Address:No.21 Renming Road, Longgang Town, Yandu County,Yancheng City
Wuhan Chemwish Technology Co., Ltd

website:http://www.chemwish.com/

Contact:+86-27-67849912

Address:Room 1311, Unit 2, Block1, Innovation Road East Lake High-tech Development Zone Wuhan, Hubei，P.R. China

Relevant to this article

Reversal of Diastereoselectivity in the Addition of C-Nucleophiles to N-Trimethylsilyl Imines via Grignard Derived Organo Copper-Boron Trifluoride Reagents.

Doi:10.1016/0040-4039(93)88045-K
(1992)
Formation of Urea, Isourea, and Triazine Derivatives from Diisopropylcyanamide with Trifluoroacetic Anhydride and Trifluoromethanesulfonic Anhydride: Thermal Instability of Urea and Isourea Derivatives

Doi:10.1021/jo9710184
(1997)
Doi:10.1039/C19650000010
()
From Compounds to Materials: Heterodinuclear Complexes as Precursors in the Synthesis of Mixed Oxides; Crystal Structures of A)> and <A)NO3)(dmso)>2>*2dmso A = N,N'-ethylenebis(3-hydroxysalicylideneimine),

Doi:10.1039/DT9910002145
(1991)
Synthesis and biological evaluation of novel N-substituted nipecotic acid derivatives with an alkyne spacer as GABA uptake inhibitors

Doi:10.1016/j.bmc.2018.05.049
(2018)
Imaging agent of a TRPA1 inhibitor

Doi:10.1002/jlcr.3030
(2013)

Article Doi