DEFLUORINATIVE COUPLING REACTIONS OF gem-DIFLUOROOLEFINS WITH ORGANOLITHIUM REAGENTS. NOVEL, FACILE METHODS FOR CHAIN ELONGATIONS OF ALDEHYDES LEADING TO AMIDES, ACETYLENES, AND KETONES

DOI: 10.1246/cl.1980.935

Source and publish data:

Chemistry Letters p. 935 - 938 (1980)

Update date:2022-08-04

Topics:

Authors:

Hayashi, Sei-ichi

Nakai, Takeshi

Ishikawa, Nobuo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1980.935

Three types of coupling reactions of gem-difluoroolefins derived easily from aldehydes with lithium reagents (R'Li and R'2NLi) are described which constitute the facile procedures for conversions of aldehydes (RCHO) to amides (RCH2CONR'2), acetylenes (RCCR'), and ketones (RCH2COR').

Full text of DOI:10.1246/cl.1980.935

Products guided by the article

Product name:((Z)-1-Fluoro-oct-1-enyl)-benzene

Cas No:75958-85-9

R&D Labs maybe for 75958-85-9

HANWAYS CHEMPHARM CO.,LIMITED

website:http://www.hanwayschem.com

Contact:+86-18502787239(whatsapp)-

Address:18-1-802, Green Garden, Jianghan District, Wuhan 430023, China
Shanxi Tongji Pharmaceuticals Co., Ltd.

Contact:+86-359-3024784

Address:Xikuang South Road, Ruicheng County , Shanxi
Jinan Hongfangde Pharmatech Co.,Ltd

Contact:86-531-88870908

Address:F Bldg. West Unit North Area of Univ. Tech. Garden Xinyu Rd. Jinan New & High Tech Industry Development Zone Shandong, China
JIANGXI ZHANGFENG CHEMICAL CO., LTD.

Contact:+86-0799-3413066

Address:Xiyuan village, Xiabu Town, Xiangdong District
Henan Harvest Chem Co., Ltd

Contact:+86-371-86058576

Address:NO.32, Jingsan Road, Zhengzhou, China

Relevant to this article

Design, synthesis and biological evaluation of novel pteridinone derivatives as potent dual inhibitors of PLK1 and BRD4

Doi:10.1039/d0nj03477k
(2020)
Total synthesis of (±) negamycin

Doi:10.1016/0040-4020(80)80072-X
(1980)
Substitution and S-alkylation reactions of thiocarbonyl-bridged Cp₂Fe₂(CO)₃CS

Doi:10.1021/ic50218a033
(1981)
Synthesis and fungicidal activity of novel chloro-containing 1-Aryl-3-oxypyrazoles with an oximino ester or oximino amide moiety

Doi:10.3390/molecules19068140
(2014)
Unprecedented acetylation of phenols using a catalytic amount of magnesium powder

Doi:10.1080/00397911.2018.1459721
(2018)
Synthesis of Phthalonitriles by Nitro Displacement

Doi:10.1055/s-1980-29135
(1980)

Article Doi