Nature of the Slow Step in the Hydrolysis of Cyclic and Bicyclic Ortho Esters Containing 1,3-Dioxane Rings

DOI: 10.1021/jo00318a013

Source and publish data:

Journal of Organic Chemistry p. 886 - 891 (1981)

Update date:2022-08-04

Topics: Hydrolysis Cyclic Bicyclic

Authors:

McClelland, Robert A.

Gedge, Sherrin

Bohonek, Jon

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Article abstract of DOI:10.1021/jo00318a013

A kinetic investigation is reported of the hydrolysis of a series of ortho esters containing 1,3-dioxane rings.Included are monocyclic 2-aryl-2-methoxy-1,3-dioxanes and bicyclic 1-aryl-4-methyl-2,6,7-trioxabicyclo<2.2.2>octanes.Both types of compounds exh

Full text of DOI:10.1021/jo00318a013

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