Tetrahedron Letters p. 2587 - 2590 (1980)
Update date:2022-08-05
Topics:
Craig, J. Cymerman
Ekwuribe, Nnochiri N.
A facile prototropic rearrangement of N-(prop-2-ynyl)amines to 1-aminopropa-1,2-dienes, followed by acid hydrolysis, affords a novel synthesis of α,β-unsaturated aldehydes.The mechanism of the reaction has been examined by deuterium labeling.
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Doi:10.1002/ardp.19833160309
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