SYNTHESIS OF PYRROLOINDOLES: VILSMEIER FORMYLATION OF SOME 3-METHYLINDOL-2-YL KETONES AND 3(3-METHYLINDOL-2-YL)PROPENOIC ESTER

DOI: 10.1016/0040-4020(80)80102-5

Source and publish data:

Tetrahedron p. 2125 - 2132 (1980)

Update date:2022-08-05

Topics: Synthesis Pyrrolo<1,2-a>indoles

Authors:

Kazembe, Takawira, C.-G

Taylor, Deryck, A.

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Article abstract of DOI:10.1016/0040-4020(80)80102-5

3-Methylindol-2-yl methyl ketone reacted with phosphoryl chloride in dimethylformamide to give 3-chloro-3(3-methylindol-2-yl)propenal (4). 2-Carbomethoxy- and 2-carbethoxy-1-chloro-9H-pyrrolo<1,2-a>indol-9-ylidene acetaldehyde (10a and b) were formed by r

Full text of DOI:10.1016/0040-4020(80)80102-5

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