Organic Letters p. 1220 - 1223 (2017)
Update date:2022-08-05
Topics:
Hou, Wen-Yi
Wu, Yen-Ku
Described is a method for the formal γ-arylation of cyclohexenones allowing synthesis of a remote all-carbon quaternary center. The process involves the palladium-catalyzed α-arylation of a α-substituted cyclic vinylogous ester followed by the Stork-Danheiser transposition. The synthetic utility of this protocol is featured in the total syntheses of (±)-12-hydroxy-13-methylpodocarpa-8,11,13-trien-3-one, (±)-3β,12-dihydroxy-13-methylpodocarpane-8,11,13-triene, and (±)-O-methyl nimbinone.
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Doi:10.1016/j.bmcl.2008.06.072
(2008)Doi:10.1016/j.tet.2009.07.015
(2009)Doi:10.1016/j.bioorg.2014.07.011
(2014)Doi:10.1016/j.bmc.2003.12.037
(2004)Doi:10.1016/j.jmmm.2019.165953
(2020)Doi:10.1021/ja01491a039
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