TRAPPING THE INTERMEDIATE INVOLVED IN THE INTRAMOLECULAR CYCLISATION OF CYCLOPROPYL KETONES. A CONVENIENT PREPARATION OF OPEN-CHAIN γ-HYDROXY KETONES.

DOI: 10.1016/S0040-4039(00)78730-2

Source and publish data:

Tetrahedron Letters p. 3517 - 3520 (1980)

Update date:2022-08-02

Topics:

Authors:

Murphy, William S.

Wattanasin, Sompong

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)78730-2

The concerted mechanism for the stannic chloride catalysed cyclisation of aryl cyclopropyl ketones is disproved by trapping the intermediate.The reaction provides a facile route to γ-hydroxyketones.

Full text of DOI:10.1016/S0040-4039(00)78730-2

Products guided by the article

Product name:(R)-2-[(S)-Hydroxy-(4-methoxy-phenyl)-methyl]-4-(3-methoxy-phenyl)-4-oxo-butyric acid ethyl ester

Cas No:76934-66-2

R&D Labs maybe for 76934-66-2

SPE Chemicals Co.,Ltd

Contact:

Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District
Laizhou City Laiyu Chemical CO.,Ltd

Contact:+86-535-2719337/2719339

Address:Chenggang road zhuyou laizhou City Shangdong China
Lishui Nanming Chemical Co., Ltd(expird)

Contact:+86-0578-2134101，2697830

Address:No.19 Tongji Road Shuige Industrial zone
Liao Cheng All Win Chemicals Co.,LTD

Contact:86+0635-2991582

Address:Room 402,Unit 1,No.27 building.Zhong tong shi dai haoyuan,liaocheng city,Shan dong Province.China
JIANGXI AIFEIMU TECHNOLOGY CO.，LTD

Contact:+86-570-6040289

Address:FINECHEMICAL PARK,ZIBU TOWN,WANNIAN COUNTY,JIANGXI PROV.,CHINA,ZIP

Relevant to this article

Isolation and Characterisation of 1,2,3,5,6,11b-Hexahydroimidazo<1,2-d><1,4>benzoxazepine from an Aziridine Ligand Reaction

Doi:10.1021/jo00324a043
(1981)
AuCl₃-catalyzed synthesis of highly substituted furans from 2-(1-alkynyl)-2-alken-1-ones

Doi:10.1021/ja0466964
(2004)
Structure-guided design of pyrazolo[1,5-a]pyrimidines as inhibitors of human cyclin-dependent kinase 2

Doi:10.1016/j.bmcl.2004.12.073
(2005)
Substituent Effects on Vinyl Radical Cyclizations onto Aryl Rings

Doi:10.1021/jo971399l
(1998)
Diastereoselective Synthesis of Nitroaldol Derivatives

Doi:10.1002/hlca.19820650402
(1982)
Highly stereoselective radical carbonylations of gem-dihalocyclopropane derivatives with CO

Doi:10.1021/ol062673d
(2007)

Article Doi