TRAPPING THE INTERMEDIATE INVOLVED IN THE INTRAMOLECULAR CYCLISATION OF CYCLOPROPYL KETONES. A CONVENIENT PREPARATION OF OPEN-CHAIN γ-HYDROXY KETONES.

DOI: 10.1016/S0040-4039(00)78730-2

Source and publish data:

Tetrahedron Letters p. 3517 - 3520 (1980)

Update date:2022-08-02

Topics:

Authors:

Murphy, William S.

Wattanasin, Sompong

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Article abstract of DOI:10.1016/S0040-4039(00)78730-2

The concerted mechanism for the stannic chloride catalysed cyclisation of aryl cyclopropyl ketones is disproved by trapping the intermediate.The reaction provides a facile route to γ-hydroxyketones.

Full text of DOI:10.1016/S0040-4039(00)78730-2

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